Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis

Anionic hypercoordinated silicates with weak donors were proposed as key intermediates in numerous silicon‐based reactions. However, their short‐lived nature rendered even spectroscopic observations highly challenging. Here, we characterize hypercoordinated silicon anions, including the first bromid...

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Detalles Bibliográficos
Autores principales: Ansmann, Nils, Hartmann, Deborah, Sailer, Sonja, Erdmann, Philipp, Maskey, Rezisha, Schorpp, Marcel, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325378/
https://www.ncbi.nlm.nih.gov/pubmed/35438836
http://dx.doi.org/10.1002/anie.202203947

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325378/
https://www.ncbi.nlm.nih.gov/pubmed/35438836
http://dx.doi.org/10.1002/anie.202203947

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