syn‐Selective Epoxidation of Chiral Terminal Allylic Alcohols with a Titanium Salalen Catalyst and Hydrogen Peroxide

In the Sharpless asymmetric epoxidation of chiral secondary allylic alcohols, one substrate enantiomer is predominantly converted to the anti‐epoxy alcohol. We herein report the first highly syn‐selective epoxidation of terminal allylic alcohols using a titanium salalen complex as catalyst, at room...

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Detalles Bibliográficos
Autores principales: Severin, Fabian, Fusi, Giovanni M., Wartmann, Christina, Neudörfl, Jörg‐Martin, Berkessel, Albrecht
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325473/
https://www.ncbi.nlm.nih.gov/pubmed/35349213
http://dx.doi.org/10.1002/anie.202201790

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325473/
https://www.ncbi.nlm.nih.gov/pubmed/35349213
http://dx.doi.org/10.1002/anie.202201790

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