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syn‐Selective Epoxidation of Chiral Terminal Allylic Alcohols with a Titanium Salalen Catalyst and Hydrogen Peroxide
In the Sharpless asymmetric epoxidation of chiral secondary allylic alcohols, one substrate enantiomer is predominantly converted to the anti‐epoxy alcohol. We herein report the first highly syn‐selective epoxidation of terminal allylic alcohols using a titanium salalen complex as catalyst, at room...
Autores principales: | Severin, Fabian, Fusi, Giovanni M., Wartmann, Christina, Neudörfl, Jörg‐Martin, Berkessel, Albrecht |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325473/ https://www.ncbi.nlm.nih.gov/pubmed/35349213 http://dx.doi.org/10.1002/anie.202201790 |
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