First Example of Fluorinated Phenanthroline Diamides: Synthesis, Structural Study, and Complexation with Lanthanoids

An efficient approach to the synthesis of diamides of 4,7-difluoro-1,10-phenanthroline-2,9-dicarboxylic acid was elaborated. Direct nucleophilic substitution with 4,7-dichloro-1,10-phenanthroline precursors opened access to difluoro derivatives in high yield. As a result, four new fluorinated ligand...

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Detalles Bibliográficos
Autores principales: Avagyan, Nane A., Lemport, Pavel S., Lysenko, Konstantin A., Gudovannyy, Alexey O., Roznyatovsky, Vitaly A., Petrov, Valentine S., Vokuev, Mikhail F., Ustynyuk, Yuri A., Nenajdenko, Valentine G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9330590/
https://www.ncbi.nlm.nih.gov/pubmed/35897882
http://dx.doi.org/10.3390/molecules27154705