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Rigid N(3)O(2)-Pentadentate Ligand-Assisted Octacoordinate Mononuclear Ln(III) Complexes: Syntheses, Characterization, and Slow Magnetization Relaxation
[Image: see text] A series of air-stable mononuclear octacoordinate Ln(III) complexes, [(L)Ln(TPPO)(3)]OTf (Ln = Y (1·Y); Gd (1·Gd); Tb (1·Tb); Dy (1·Dy); Ho (1·Ho); and Er (1·Er)) and [(L)Ln(TPPO)(NO(3))] (Ln = Y (2·Y) and Dy (2·Dy)), are synthesized employing a rigid N(3)O(2)-pentadentate chelatin...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9330846/ https://www.ncbi.nlm.nih.gov/pubmed/35910178 http://dx.doi.org/10.1021/acsomega.2c03631 |