Rigid N(3)O(2)-Pentadentate Ligand-Assisted Octacoordinate Mononuclear Ln(III) Complexes: Syntheses, Characterization, and Slow Magnetization Relaxation

[Image: see text] A series of air-stable mononuclear octacoordinate Ln(III) complexes, [(L)Ln(TPPO)(3)]OTf (Ln = Y (1·Y); Gd (1·Gd); Tb (1·Tb); Dy (1·Dy); Ho (1·Ho); and Er (1·Er)) and [(L)Ln(TPPO)(NO(3))] (Ln = Y (2·Y) and Dy (2·Dy)), are synthesized employing a rigid N(3)O(2)-pentadentate chelatin...

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Detalles Bibliográficos
Autores principales: Singh, Vaibhav, Das, Dhiraj, Anga, Srinivas, Sutter, Jean-Pascal, Chandrasekhar, Vadapalli, Bar, Arun Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9330846/
https://www.ncbi.nlm.nih.gov/pubmed/35910178
http://dx.doi.org/10.1021/acsomega.2c03631

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