Trityl Cation-Catalyzed Hosomi-Sakurai Reaction of Allylsilane with β,γ-Unsaturated α-Ketoester to Form γ,γ-Disubstituted α-Ketoesters

(Ph(3)C)[BPh((F))(4)]-catalyzed Hosomi-Sakurai allylation of allylsilanes with β,γ-unsaturated α-ketoesters has been developed to give γ,γ-disubstituted α-ketoesters in high yields with excellent chemoselectivity. Preliminary mechanistic studies suggest that trityl cation dominates the catalysis, wh...

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Detalles Bibliográficos
Autores principales: Gan, Zubao, Cui, Deyun, Zhang, Hongyun, Feng, Ying, Huang, Liying, Gui, Yingying, Gao, Lu, Song, Zhenlei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9331905/
https://www.ncbi.nlm.nih.gov/pubmed/35897907
http://dx.doi.org/10.3390/molecules27154730

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9331905/
https://www.ncbi.nlm.nih.gov/pubmed/35897907
http://dx.doi.org/10.3390/molecules27154730

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