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A Study on the Direct Esterification of Monoalkylphosphates and Dialkylphosphates; The Conversion of the Latter Species to Trialkylphosphates by Alkylating Esterification †

The microwave (MW)-assisted direct esterification of certain P-acids is a green method. Quantum chemical calculations revealed that the activation enthalpy (ΔH(#)) for the exothermic monoalkylphosphate → dialkylphosphate transformation was on the average 156.6 kJ mol(−1), while ΔH(#) for the dialkyl...

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Detalles Bibliográficos
Autores principales: Ábrányi-Balogh, Péter, Harsági, Nikoletta, Drahos, László, Keglevich, György
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9331942/
https://www.ncbi.nlm.nih.gov/pubmed/35897850
http://dx.doi.org/10.3390/molecules27154674