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A Study on the Direct Esterification of Monoalkylphosphates and Dialkylphosphates; The Conversion of the Latter Species to Trialkylphosphates by Alkylating Esterification †
The microwave (MW)-assisted direct esterification of certain P-acids is a green method. Quantum chemical calculations revealed that the activation enthalpy (ΔH(#)) for the exothermic monoalkylphosphate → dialkylphosphate transformation was on the average 156.6 kJ mol(−1), while ΔH(#) for the dialkyl...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9331942/ https://www.ncbi.nlm.nih.gov/pubmed/35897850 http://dx.doi.org/10.3390/molecules27154674 |