Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects

[Image: see text] The mechanistic details of the ((Ph)BPE)Co-catalyzed asymmetric hydrogenation of enamides are investigated using computational and experimental approaches. Four mechanistic possibilities are compared: a direct Co(0)/Co(II) redox path, a metathesis pathway, a nonredox Co(II) mechani...

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Detalles Bibliográficos
Autores principales: Pavlovic, Ljiljana, Mendelsohn, Lauren N., Zhong, Hongyu, Chirik, Paul J., Hopmann, Kathrin H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9335863/
https://www.ncbi.nlm.nih.gov/pubmed/35915664
http://dx.doi.org/10.1021/acs.organomet.2c00180

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9335863/
https://www.ncbi.nlm.nih.gov/pubmed/35915664
http://dx.doi.org/10.1021/acs.organomet.2c00180

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