Fe-Catalyzed Selective Formal Insertion of Diazo Compounds into C(sp)–C(sp(3)) Bonds of Propargyl Alcohols: Access to Alkyne-Substituted All-Carbon Quaternary Centers

[Image: see text] The construction of all-carbon quaternary centers, especially those containing an alkyne-substituted framework, represents an important challenge in organic synthesis. Here we present a novel Fe-catalyzed selective formal insertion of diazo compounds into C(sp)–C(sp(3)) bonds of pr...

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Detalles Bibliográficos
Autores principales: Wang, Dong-Kai, Li, Liu-Bin, Liu, Fa-Liang, Qiu, Hui, Li, Jiao-Zhe, Zhang, Jianfeng, Deng, Chao, Wei, Wen-Ting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9336152/
https://www.ncbi.nlm.nih.gov/pubmed/35912339
http://dx.doi.org/10.1021/acscentsci.2c00204

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9336152/
https://www.ncbi.nlm.nih.gov/pubmed/35912339
http://dx.doi.org/10.1021/acscentsci.2c00204

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