Nickel(II)-catalyzed asymmetric photoenolization/Mannich reaction of (2-alkylphenyl) ketones

A diastereo- and enantioselective photoenolization/Mannich (PEM) reaction of ortho-alkyl aromatic ketones with benzosulfonimides was established by utilizing a chiral N,N′-dioxide/Ni(OTf)(2) complex as the Lewis acid catalyst. It afforded a series of benzosulfonamides and the corresponding ring-clos...

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Detalles Bibliográficos
Autores principales: Yang, Liangkun, Li, Wang-Yuren, Hou, Liuzhen, Zhan, Tangyu, Cao, Weidi, Liu, Xiaohua, Feng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337722/
https://www.ncbi.nlm.nih.gov/pubmed/35974747
http://dx.doi.org/10.1039/d2sc02721f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337722/
https://www.ncbi.nlm.nih.gov/pubmed/35974747
http://dx.doi.org/10.1039/d2sc02721f

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