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Cooperative B–H bond activation: dual site borane activation by redox active κ(2)-N,S-chelated complexes

Cooperative dual site activation of boranes by redox-active 1,3-N,S-chelated ruthenium species, mer-[PR(3){κ(2)-N,S-(L)}(2)Ru{κ(1)-S-(L)}], (mer-2a: R = Cy, mer-2b: R = Ph; L = NC(7)H(4)S(2)), generated from the aerial oxidation of borate complexes, [PR(3){κ(2)-N,S-(L)}Ru{κ(3)-H,S,S′-BH(2)(L)(2)}] (...

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Detalles Bibliográficos
Autores principales: Zafar, Mohammad, Ahmad, Asif, Saha, Suvam, Ramalakshmi, Rongala, Roisnel, Thierry, Ghosh, Sundargopal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337726/
https://www.ncbi.nlm.nih.gov/pubmed/35974760
http://dx.doi.org/10.1039/d2sc00907b