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Cooperative B–H bond activation: dual site borane activation by redox active κ(2)-N,S-chelated complexes
Cooperative dual site activation of boranes by redox-active 1,3-N,S-chelated ruthenium species, mer-[PR(3){κ(2)-N,S-(L)}(2)Ru{κ(1)-S-(L)}], (mer-2a: R = Cy, mer-2b: R = Ph; L = NC(7)H(4)S(2)), generated from the aerial oxidation of borate complexes, [PR(3){κ(2)-N,S-(L)}Ru{κ(3)-H,S,S′-BH(2)(L)(2)}] (...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337726/ https://www.ncbi.nlm.nih.gov/pubmed/35974760 http://dx.doi.org/10.1039/d2sc00907b |