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Carbocation catalysis in confined space: activation of trityl chloride inside the hexameric resorcinarene capsule
Carbocation catalysis can be performed inside the confined space of the hexameric resorcinarene capsule. The inner cavity of the capsule can host the trityl carbocation, which catalyses the Diels–Alder reaction between dienes and unsaturated aldehydes. Experimental results and in silico calculations...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337730/ https://www.ncbi.nlm.nih.gov/pubmed/35974771 http://dx.doi.org/10.1039/d2sc02901d |