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Carbocation catalysis in confined space: activation of trityl chloride inside the hexameric resorcinarene capsule

Carbocation catalysis can be performed inside the confined space of the hexameric resorcinarene capsule. The inner cavity of the capsule can host the trityl carbocation, which catalyses the Diels–Alder reaction between dienes and unsaturated aldehydes. Experimental results and in silico calculations...

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Detalles Bibliográficos
Autores principales: De Rosa, Margherita, Gambaro, Stefania, Soriente, Annunziata, Della Sala, Paolo, Iuliano, Veronica, Talotta, Carmen, Gaeta, Carmine, Rescifina, Antonio, Neri, Placido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337730/
https://www.ncbi.nlm.nih.gov/pubmed/35974771
http://dx.doi.org/10.1039/d2sc02901d