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Divergent synthesis of benzazepines and bridged polycycloalkanones via dearomative rearrangement
The dearomative functionalization of aromatic compounds represents a fascinating but challenging transformation, as it typically needs to overcome a great kinetic barrier. Here, a catalyst-free dearomative rearrangement of o-nitrophenyl alkyne is successfully established by leveraging the remote oxy...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9338057/ https://www.ncbi.nlm.nih.gov/pubmed/35906217 http://dx.doi.org/10.1038/s41467-022-31920-1 |