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Divergent synthesis of benzazepines and bridged polycycloalkanones via dearomative rearrangement

The dearomative functionalization of aromatic compounds represents a fascinating but challenging transformation, as it typically needs to overcome a great kinetic barrier. Here, a catalyst-free dearomative rearrangement of o-nitrophenyl alkyne is successfully established by leveraging the remote oxy...

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Detalles Bibliográficos
Autores principales: Shi, Qiu, Liao, Zhehui, Liu, Zhili, Wen, Jiajia, Li, Chenguang, He, Jiamin, Deng, Jiazhen, Cen, Shan, Cao, Tongxiang, Zhou, Jinming, Zhu, Shifa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9338057/
https://www.ncbi.nlm.nih.gov/pubmed/35906217
http://dx.doi.org/10.1038/s41467-022-31920-1