Fluoride-bridged dinuclear dysprosium complex showing single-molecule magnetic behavior: supramolecular approach to isolate magnetic molecules

Using Na-encapsulated benzo[18]crown-6 (Na)(B18C6) as a counter cation, we successfully magnetically isolated a fluoride-bridging Dy dinuclear complex {[(PW(11)O(39))Dy(H(2)O)(2)](2)F} (Dy(2)POM) with lacunary Keggin ligands. (Na)(B18C6) formed two types of tetramers through C–H⋯O, π⋯π and C–H⋯π int...

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Detalles Bibliográficos
Autores principales: Wu, Dong-Fang, Takahashi, Kiyonori, Fujibayashi, Masaru, Tsuchiya, Naoto, Cosquer, Goulven, Huang, Rui-Kang, Xue, Chen, Nishihara, Sadafumi, Nakamura, Takayoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9344285/
https://www.ncbi.nlm.nih.gov/pubmed/35975059
http://dx.doi.org/10.1039/d2ra04119g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9344285/
https://www.ncbi.nlm.nih.gov/pubmed/35975059
http://dx.doi.org/10.1039/d2ra04119g

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