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Regulated synthesis of Zr-metal–organic frameworks with variable hole size and its influence on the performance of novel MOF-based heterogeneous amino acid–thiourea catalysts

We present an efficient and easy synthesis method for incorporating organocatalytic moieties into Zr-metal organic frameworks (Zr-MOFs). The catalytic activity and selectivity of the new chiral catalysts were improved by adjusting the aperture of the MOF cavities. The hole size of the Zr-MOF was mod...

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Detalles Bibliográficos
Autores principales: Zhu, Junfeng, Meng, Xiaorong, Liu, Wen, Qi, Yabing, Jin, Siyi, Huo, Shanshan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9347210/
https://www.ncbi.nlm.nih.gov/pubmed/35975053
http://dx.doi.org/10.1039/d2ra03747e