An Artificial Metalloenzyme Based on a Copper Heteroscorpionate Enables sp(3) C–H Functionalization via Intramolecular Carbene Insertion

[Image: see text] The selective functionalization of sp(3) C–H bonds is a versatile tool for the diversification of organic compounds. Combining attractive features of homogeneous and enzymatic catalysts, artificial metalloenzymes offer an ideal means to selectively modify these inert motifs. Herein...

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Detalles Bibliográficos
Autores principales: Rumo, Corentin, Stein, Alina, Klehr, Juliane, Tachibana, Ryo, Prescimone, Alessandro, Häussinger, Daniel, Ward, Thomas R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348757/
https://www.ncbi.nlm.nih.gov/pubmed/35749305
http://dx.doi.org/10.1021/jacs.2c03311

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348757/
https://www.ncbi.nlm.nih.gov/pubmed/35749305
http://dx.doi.org/10.1021/jacs.2c03311

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