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An Artificial Metalloenzyme Based on a Copper Heteroscorpionate Enables sp(3) C–H Functionalization via Intramolecular Carbene Insertion
[Image: see text] The selective functionalization of sp(3) C–H bonds is a versatile tool for the diversification of organic compounds. Combining attractive features of homogeneous and enzymatic catalysts, artificial metalloenzymes offer an ideal means to selectively modify these inert motifs. Herein...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348757/ https://www.ncbi.nlm.nih.gov/pubmed/35749305 http://dx.doi.org/10.1021/jacs.2c03311 |