Diagnosing Ring Current(s) in Figure-Eight Skeletons: A 3D Through-Space Conjugation in the Two-Loops Crossing

[Image: see text] The macrocyclic structures with local conjugation readily undergo a redox-triggered change in the diatropic character, leading to a global current–density pathway of the doubly charged systems. The figure-eight geometry of the neutral dimer does not significantly change upon oxidat...

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Detalles Bibliográficos
Autores principales: Wypych, Katarzyna, Dimitrova, Maria, Sundholm, Dage, Pawlicki, Miłosz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348834/
https://www.ncbi.nlm.nih.gov/pubmed/35796415
http://dx.doi.org/10.1021/acs.orglett.2c01625

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348834/
https://www.ncbi.nlm.nih.gov/pubmed/35796415
http://dx.doi.org/10.1021/acs.orglett.2c01625

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