Stereoselective Cyclopropanation of 1,1-Diborylalkenes via Palladium-Catalyzed (Trimethylsilyl)diazomethane Insertion

[Image: see text] Palladium catalyzes the cyclopropanation of 2-substituted 1,1-diborylalkenes with (trimethylsilyl)diazomethane. The relative stereoselectivity is controlled via a carbene insertion sequence generating an exclusive anti conformation between the R and SiMe(3) substituents. Mixed 1,1-...

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Detalles Bibliográficos
Autores principales: Salvado, Oriol, Dominguez-Molano, Paula, Fernández, Elena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348837/
https://www.ncbi.nlm.nih.gov/pubmed/35796357
http://dx.doi.org/10.1021/acs.orglett.2c01885

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348837/
https://www.ncbi.nlm.nih.gov/pubmed/35796357
http://dx.doi.org/10.1021/acs.orglett.2c01885

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