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Coordination and Homologation of CO at Al(I): Mechanism and Chain Growth, Branching, Isomerization, and Reduction

[Image: see text] Homologation of carbon monoxide is central to the heterogeneous Fischer–Tropsch process for the production of hydrocarbon fuels. C–C bond formation has been modeled by homogeneous systems, with [C(n)O(n)](2–) fragments (n = 2–6) formed by two-electron reduction being commonly encou...

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Detalles Bibliográficos
Autores principales: Heilmann, Andreas, Roy, Matthew M. D., Crumpton, Agamemnon E., Griffin, Liam P., Hicks, Jamie, Goicoechea, Jose M., Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348839/
https://www.ncbi.nlm.nih.gov/pubmed/35786888
http://dx.doi.org/10.1021/jacs.2c05228