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Cobalt-catalyzed branched selective hydroallylation of terminal alkynes

Here, we reported a cobalt-hydride-catalyzed Markovnikov-type hydroallylation of terminal alkynes with allylic electrophile to access valuable and branched skipped dienes (1,4-dienes) with good regioselectivity. This operationally simple protocol exhibits excellent functional group tolerance and exc...

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Detalles Bibliográficos
Autores principales: Chen, Jieping, Ying, Jiale, Lu, Zhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9349270/
https://www.ncbi.nlm.nih.gov/pubmed/35922446
http://dx.doi.org/10.1038/s41467-022-32291-3