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Iridium-catalyzed α-selective deuteration of alcohols
The development of chemoselective C(sp(3))-H deuteration is of particular interest in synthetic chemistry. We herein report the α-selective, iridium(iii)-bipyridonate-catalyzed hydrogen(H)/deuterium(D) isotope exchange of alcohols using deuterium oxide (D(2)O) as the primary deuterium source. This m...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9350590/ https://www.ncbi.nlm.nih.gov/pubmed/35975159 http://dx.doi.org/10.1039/d2sc01805e |