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Tuning the Ground- and Excited-State Redox Potentials of Octahedral Hexanuclear Rhenium(III) Complexes by the Combination of Terminal Halide and N-Heteroaromatic Ligands

[Image: see text] The present study reports that the ground- and excited-state Re(6)(23e)/Re(6)(24e) redox potentials of an octahedral hexanuclear rhenium(III) complex can be controlled by systematically changing the number and type of the N-heteroaromatic ligand (L) and the number of chloride ions...

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Detalles Bibliográficos
Autores principales: Yoshimura, Takashi, Nishizawa, Hayato, Nagata, Kojiro, Ito, Akitaka, Sakuda, Eri, Ishizaka, Shoji, Kitamura, Noboru, Shinohara, Atsushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9352233/
https://www.ncbi.nlm.nih.gov/pubmed/35936475
http://dx.doi.org/10.1021/acsomega.2c03834