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Mechanistic Facets of the Competition between Cross-Coupling and Homocoupling in Supporting Ligand-Free Iron-Mediated Aryl–Aryl Bond Formations

[Image: see text] In the context of cross-coupling chemistry, the competition between the cross-coupling path itself and the oxidative homocoupling of the nucleophile is a classic issue. In that case, the electrophilic partner acts as a sacrificial oxidant. We investigate in this report the factors...

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Detalles Bibliográficos
Autores principales: Zhou, Edouard, Chourreu, Pablo, Lefèvre, Nicolas, Ahr, Mathieu, Rousseau, Lidie, Herrero, Christian, Gayon, Eric, Cahiez, Gérard, Lefèvre, Guillaume
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9354087/
https://www.ncbi.nlm.nih.gov/pubmed/35942278
http://dx.doi.org/10.1021/acsorginorgau.2c00002