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Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol

[Image: see text] Current models for oxazaborolidine-catalyzed transition-state structures are determined by C–H···O–B and C–H···O=S formyl hydrogen bonding between the electrophile and catalyst. However, selectivity in the oxazaborolidine-catalyzed Mukaiyama aldol cannot be fully rationalized using...

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Detalles Bibliográficos
Autores principales: Farrar, Elliot H. E., Grayson, Matthew N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361351/
https://www.ncbi.nlm.nih.gov/pubmed/35849546
http://dx.doi.org/10.1021/acs.joc.2c01039