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Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol
[Image: see text] Current models for oxazaborolidine-catalyzed transition-state structures are determined by C–H···O–B and C–H···O=S formyl hydrogen bonding between the electrophile and catalyst. However, selectivity in the oxazaborolidine-catalyzed Mukaiyama aldol cannot be fully rationalized using...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361351/ https://www.ncbi.nlm.nih.gov/pubmed/35849546 http://dx.doi.org/10.1021/acs.joc.2c01039 |