From a Möbius-aromatic interlocked Mn(2)B(10)H(10) wheel to the metal-doped boranaphthalenes M(2)@B(10)H(8) and M(2)B(5) 2D-sheets (M = Mn and Fe): a molecules to materials continuum using DFT studies

The inherent tendency of BR fragments to undergo coupling is utilized to predict M(2)B(10)H(10) and M(2)@B(10)H(8) complexes (where M = Mn and Fe). Electronic structure analysis of Mn(2)B(10)H(10) (7) shows that the metal d-orbitals stabilize the interlocked boron wheel structure, forming an unprece...

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Detalles Bibliográficos
Autores principales: Ghorai, Sagar, Jemmis, Eluvathingal D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9365082/
https://www.ncbi.nlm.nih.gov/pubmed/36091213
http://dx.doi.org/10.1039/d2sc02244c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9365082/
https://www.ncbi.nlm.nih.gov/pubmed/36091213
http://dx.doi.org/10.1039/d2sc02244c

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