Spin-induced asymmetry reaction—The formation of asymmetric carbon by electropolymerization

We describe the spin polarization–induced chirogenic electropolymerization of achiral 2-vinylpyridine, which forms a layer of enantioenhanced isotactic polymer on the electrode. The product formed is enantioenriched in asymmetric carbon polymer. To confirm the chirality of the polymer film formed on...

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Detalles Bibliográficos
Autores principales: Bhowmick, Deb Kumar, Das, Tapan Kumar, Santra, Kakali, Mondal, Amit Kumar, Tassinari, Francesco, Schwarz, Rony, Diesendruck, Charles E., Naaman, Ron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Physical and Materials Sciences
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9365291/
https://www.ncbi.nlm.nih.gov/pubmed/35947656
http://dx.doi.org/10.1126/sciadv.abq2727

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9365291/
https://www.ncbi.nlm.nih.gov/pubmed/35947656
http://dx.doi.org/10.1126/sciadv.abq2727

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