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IR-Spectroscopic and X-ray-Structural Study of Vinyl-Type Carbocations in Their Carborane Salts
[Image: see text] The butylene carbocation in its salts with anions CHB(11)F(11)(–) and CHB(11)Cl(11)(–) forms isomers CH(2)=C(+)–CH(2)–CH(3) (I) and CH(3)–C(+)=CH–CH(3) (II), which were characterized here by infrared (IR) spectroscopy and X-ray diffraction analysis. The strongest influence on the s...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9366973/ https://www.ncbi.nlm.nih.gov/pubmed/35967019 http://dx.doi.org/10.1021/acsomega.2c03025 |