A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

A series of Au(i)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(i...

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Detalles Bibliográficos
Autores principales: Hidalgo, Nereida, de la Cruz-Martínez, Felipe, Martín, M. Trinidad, Nicasio, M. Carmen, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367266/
https://www.ncbi.nlm.nih.gov/pubmed/35894238
http://dx.doi.org/10.1039/d2cc03089f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367266/
https://www.ncbi.nlm.nih.gov/pubmed/35894238
http://dx.doi.org/10.1039/d2cc03089f

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