A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

A series of Au(i)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(i...

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Detalles Bibliográficos
Autores principales: Hidalgo, Nereida, de la Cruz-Martínez, Felipe, Martín, M. Trinidad, Nicasio, M. Carmen, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367266/
https://www.ncbi.nlm.nih.gov/pubmed/35894238
http://dx.doi.org/10.1039/d2cc03089f
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author Hidalgo, Nereida
de la Cruz-Martínez, Felipe
Martín, M. Trinidad
Nicasio, M. Carmen
Campos, Jesús
author_facet Hidalgo, Nereida
de la Cruz-Martínez, Felipe
Martín, M. Trinidad
Nicasio, M. Carmen
Campos, Jesús
author_sort Hidalgo, Nereida
collection PubMed
description A series of Au(i)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(ii) structure.
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spelling pubmed-93672662022-09-08 A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation Hidalgo, Nereida de la Cruz-Martínez, Felipe Martín, M. Trinidad Nicasio, M. Carmen Campos, Jesús Chem Commun (Camb) Chemistry A series of Au(i)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(ii) structure. The Royal Society of Chemistry 2022-07-19 /pmc/articles/PMC9367266/ /pubmed/35894238 http://dx.doi.org/10.1039/d2cc03089f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Hidalgo, Nereida
de la Cruz-Martínez, Felipe
Martín, M. Trinidad
Nicasio, M. Carmen
Campos, Jesús
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
title A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
title_full A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
title_fullStr A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
title_full_unstemmed A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
title_short A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
title_sort highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367266/
https://www.ncbi.nlm.nih.gov/pubmed/35894238
http://dx.doi.org/10.1039/d2cc03089f
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