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A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
A series of Au(i)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(i...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367266/ https://www.ncbi.nlm.nih.gov/pubmed/35894238 http://dx.doi.org/10.1039/d2cc03089f |