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Four-Coordinate Fe N(2) and Imido Complexes Supported by a Hemilabile NNC Heteroscorpionate Ligand
[Image: see text] Inspired by mechanistic proposals for N(2) reduction at the nitrogenase FeMo cofactor, we report herein a new, strongly σ-donating heteroscorpionate ligand featuring two weak-field pyrazoles and an alkyl donor. This ligand supports four-coordinate Fe(I)-N(2), Fe(II)-Cl, and Fe(III)...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367695/ https://www.ncbi.nlm.nih.gov/pubmed/35895990 http://dx.doi.org/10.1021/acs.inorgchem.2c01656 |