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Four-Coordinate Fe N(2) and Imido Complexes Supported by a Hemilabile NNC Heteroscorpionate Ligand

[Image: see text] Inspired by mechanistic proposals for N(2) reduction at the nitrogenase FeMo cofactor, we report herein a new, strongly σ-donating heteroscorpionate ligand featuring two weak-field pyrazoles and an alkyl donor. This ligand supports four-coordinate Fe(I)-N(2), Fe(II)-Cl, and Fe(III)...

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Detalles Bibliográficos
Autores principales:	McSkimming, Alex, Thompson, Niklas B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367695/ https://www.ncbi.nlm.nih.gov/pubmed/35895990 http://dx.doi.org/10.1021/acs.inorgchem.2c01656

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