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Role of lone-pair electron localization in temperature-induced phase transitions in mimetite
The crystal structure of mimetite Pb(5)(AsO(4))(3)Cl, a phosphate with apatite structure-type has been investigated in situ at 123, 173, 273, 288, 353 and 393 K. A careful inspection of the diffraction pattern and subsequent structure refinements indicated that mimetite transforms from the monoclini...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9370212/ https://www.ncbi.nlm.nih.gov/pubmed/35975828 http://dx.doi.org/10.1107/S2052520622006254 |