Cargando…

Role of lone-pair electron localization in temperature-induced phase transitions in mimetite

The crystal structure of mimetite Pb(5)(AsO(4))(3)Cl, a phosphate with apatite structure-type has been investigated in situ at 123, 173, 273, 288, 353 and 393 K. A careful inspection of the diffraction pattern and subsequent structure refinements indicated that mimetite transforms from the monoclini...

Descripción completa

Detalles Bibliográficos
Autores principales: Cametti, Georgia, Nagashima, Mariko, Churakov, Sergey V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9370212/
https://www.ncbi.nlm.nih.gov/pubmed/35975828
http://dx.doi.org/10.1107/S2052520622006254