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Controlled Selectivity through Reversible Inhibition of the Catalyst: Stereodivergent Semihydrogenation of Alkynes

[Image: see text] Catalytic semihydrogenation of internal alkynes using H(2) is an attractive atom-economical route to various alkenes, and its stereocontrol has received widespread attention, both in homogeneous and heterogeneous catalyses. Herein, a novel strategy is introduced, whereby a poisonin...

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Detalles Bibliográficos
Autores principales: Luo, Jie, Liang, Yaoyu, Montag, Michael, Diskin-Posner, Yael, Avram, Liat, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9374179/
https://www.ncbi.nlm.nih.gov/pubmed/35839274
http://dx.doi.org/10.1021/jacs.2c04233