Shedding Light on the Oxidizing Properties of Spin-Flip Excited States in a Cr(III) Polypyridine Complex and Their Use in Photoredox Catalysis

[Image: see text] The photoredox activity of well-known Ru(II) complexes stems from metal-to-ligand charge transfer (MLCT) excited states, in which a ligand-based electron can initiate chemical reductions and a metal-centered hole can trigger oxidations. Cr(III) polypyridines show similar photoredox...

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Detalles Bibliográficos
Autores principales: Bürgin, Tobias H., Glaser, Felix, Wenger, Oliver S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9376921/
https://www.ncbi.nlm.nih.gov/pubmed/35913126
http://dx.doi.org/10.1021/jacs.2c04465

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9376921/
https://www.ncbi.nlm.nih.gov/pubmed/35913126
http://dx.doi.org/10.1021/jacs.2c04465

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