Reactivity of a Unique Si(I)–Si(I)-Based η(2)-Bis(silylene) Iron Complex

[Image: see text] In this paper, we report the synthesis of a unique silicon(I)-based metalla-disilirane and report on its reactivity toward TMS-azide and benzophenone. Metal complexes containing disilylenes ((bis)silylenes with a Si–Si bond) are known, but direct ligation of the Si(I) centers to tr...

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Detalles Bibliográficos
Autores principales: He, Zhiyuan, Liu, Lingyu, de Zwart, Felix J., Xue, Xiaolian, Ehlers, Andreas W., Yan, KaKing, Demeshko, Serhiy, van der Vlugt, Jarl Ivar, de Bruin, Bas, Krogman, Jeremy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377512/
https://www.ncbi.nlm.nih.gov/pubmed/35857413
http://dx.doi.org/10.1021/acs.inorgchem.2c01369

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377512/
https://www.ncbi.nlm.nih.gov/pubmed/35857413
http://dx.doi.org/10.1021/acs.inorgchem.2c01369

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