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Reactivity of a Unique Si(I)–Si(I)-Based η(2)-Bis(silylene) Iron Complex
[Image: see text] In this paper, we report the synthesis of a unique silicon(I)-based metalla-disilirane and report on its reactivity toward TMS-azide and benzophenone. Metal complexes containing disilylenes ((bis)silylenes with a Si–Si bond) are known, but direct ligation of the Si(I) centers to tr...
Autores principales: | He, Zhiyuan, Liu, Lingyu, de Zwart, Felix J., Xue, Xiaolian, Ehlers, Andreas W., Yan, KaKing, Demeshko, Serhiy, van der Vlugt, Jarl Ivar, de Bruin, Bas, Krogman, Jeremy |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377512/ https://www.ncbi.nlm.nih.gov/pubmed/35857413 http://dx.doi.org/10.1021/acs.inorgchem.2c01369 |
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