Chalcogen bond-guided conformational isomerization enables catalytic dynamic kinetic resolution of sulfoxides

Conformational isomerization can be guided by weak interactions such as chalcogen bonding (ChB) interactions. Here we report a catalytic strategy for asymmetric access to chiral sulfoxides by employing conformational isomerization and chalcogen bonding interactions. The reaction involves a sulfoxide...

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Detalles Bibliográficos
Autores principales: Liu, Jianjian, Zhou, Mali, Deng, Rui, Zheng, Pengcheng, Chi, Yonggui Robin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9378665/
https://www.ncbi.nlm.nih.gov/pubmed/35970848
http://dx.doi.org/10.1038/s41467-022-32428-4

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9378665/
https://www.ncbi.nlm.nih.gov/pubmed/35970848
http://dx.doi.org/10.1038/s41467-022-32428-4

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