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Chalcogen bond-guided conformational isomerization enables catalytic dynamic kinetic resolution of sulfoxides
Conformational isomerization can be guided by weak interactions such as chalcogen bonding (ChB) interactions. Here we report a catalytic strategy for asymmetric access to chiral sulfoxides by employing conformational isomerization and chalcogen bonding interactions. The reaction involves a sulfoxide...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9378665/ https://www.ncbi.nlm.nih.gov/pubmed/35970848 http://dx.doi.org/10.1038/s41467-022-32428-4 |