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Synthesis of cis-thiiranes as diastereoselective access to epoxide congeners via 4π-electrocyclization of thiocarbonyl ylides

Organochalcogen heterocycles are ubiquitously present and widely utilized in various fields. Among them, oxirane has been extensively studied, and all of the stereoisomeric forms are readily available. In contrast, synthetic studies on thiirane were rarely reported, and thus the useful sulfur-congen...

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Detalles Bibliográficos
Autores principales: Song, Su-min, Jin, Jaeseong, Choi, Jun-Ho, Chung, Won-jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9381720/
https://www.ncbi.nlm.nih.gov/pubmed/35974103
http://dx.doi.org/10.1038/s41467-022-32499-3