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Cation assisted binding and cleavage of dinitrogen by uranium complexes

The role of alkali promoters in N(2) cleavage by metal complexes remains poorly understood despite its relevance to the industrial production of ammonia from N(2). Here we report a series of alkali bound-oxo-bridged diuranium(iii) complexes that provide a unique example of decreasing N(2) binding af...

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Detalles Bibliográficos
Autores principales: Jori, Nadir, Rajeshkumar, Thayalan, Scopelliti, Rosario, Z̆ivković, Ivica, Sienkiewicz, Andrzej, Maron, Laurent, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384805/
https://www.ncbi.nlm.nih.gov/pubmed/36093011
http://dx.doi.org/10.1039/d2sc02530b