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Cation assisted binding and cleavage of dinitrogen by uranium complexes
The role of alkali promoters in N(2) cleavage by metal complexes remains poorly understood despite its relevance to the industrial production of ammonia from N(2). Here we report a series of alkali bound-oxo-bridged diuranium(iii) complexes that provide a unique example of decreasing N(2) binding af...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384805/ https://www.ncbi.nlm.nih.gov/pubmed/36093011 http://dx.doi.org/10.1039/d2sc02530b |