Towards clustered carbonyl cations [M(3)(CO)(14)](2+) (M = Ru, Os): the need for innocent deelectronation

To access the hitherto almost unknown class of clustered transition metal carbonyl cations, the trimetal dodecacarbonyls M(3)(CO)(12) (M = Ru, Os) were reacted with the oxidant Ag(+)[WCA](−), but yielded the silver complexes [Ag{M(3)(CO)(12)}(2)](+)[WCA](−) (WCA = [Al(OR(F))(4)](−), [F{Al(OR(F))(3)}...

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Detalles Bibliográficos
Autores principales: Sellin, Malte, Friedmann, Christian, Mayländer, Maximilian, Richert, Sabine, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384829/
https://www.ncbi.nlm.nih.gov/pubmed/36093020
http://dx.doi.org/10.1039/d2sc02358j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384829/
https://www.ncbi.nlm.nih.gov/pubmed/36093020
http://dx.doi.org/10.1039/d2sc02358j

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