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Towards clustered carbonyl cations [M(3)(CO)(14)](2+) (M = Ru, Os): the need for innocent deelectronation
To access the hitherto almost unknown class of clustered transition metal carbonyl cations, the trimetal dodecacarbonyls M(3)(CO)(12) (M = Ru, Os) were reacted with the oxidant Ag(+)[WCA](−), but yielded the silver complexes [Ag{M(3)(CO)(12)}(2)](+)[WCA](−) (WCA = [Al(OR(F))(4)](−), [F{Al(OR(F))(3)}...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384829/ https://www.ncbi.nlm.nih.gov/pubmed/36093020 http://dx.doi.org/10.1039/d2sc02358j |